Chemistry · Carboxylic Acids and its Derivatives
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The products of the reaction given below are:
CH3COOH + PCl5 → ?
- A
CH3COCl + POCl3 + HCl
- B
CH3COCl + POCl2 + HCl
- C
CH3Cl + POCl3 + HCl
- D
CH3COCl + POCl3 + H2
The reaction of a carboxylic acid (acetic acid in this case) and PCl5 produces an acyl chloride (CH3COCl in this case) along with POCl3 and HCl.
The reaction of a carboxylic acid (acetic acid in this case) and PCl5 produces an acyl chloride (CH3COCl in this case) along with POCl3 and HCl.
Option B is incorrect because it suggests the formation of an incorrect product, CH3COCl, and does not correctly account for the products of the reaction.
Option C is incorrect as it suggests the formation of CH3Cl, which is not a product of the given reaction between acetic acid (CH3COOH) and phosphorus pentachloride (PCl5).
Option D is incorrect because it proposes the formation of H2, which is not a product of the reaction between CH3COOH and PCl5. The reaction primarily involves the substitution of hydroxyl (-OH) groups in acetic acid with chlorine atoms from PCl5.
Tagged under Chemistry · Carboxylic Acids and its Derivatives · 2011