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  4. Carboxylic Acids and its Derivatives
MDCAT
Chemistry
2011

Chemistry · Carboxylic Acids and its Derivatives

Work through this past-paper style MCQ, then read the full explanation. Practice more chemistry questions on mMCQ with adaptive practice and topic analytics.

Question

The products of the reaction given below are:

CH3COOH + PCl5 → ?

Options
  • A

    CH3COCl + POCl3 + HCl

  • B

    CH3COCl + POCl2 + HCl

  • C

    CH3Cl + POCl3 + HCl

  • D

    CH3COCl + POCl3 + H2

Explanation

The reaction of a carboxylic acid (acetic acid in this case) and PCl5 produces an acyl chloride (CH3COCl in this case) along with POCl3 and HCl.

The reaction of a carboxylic acid (acetic acid in this case) and PCl5 produces an acyl chloride (CH3COCl in this case) along with POCl3 and HCl. 

Option B is incorrect because it suggests the formation of an incorrect product, CH3COCl, and does not correctly account for the products of the reaction. 

Option C is incorrect as it suggests the formation of CH3Cl, which is not a product of the given reaction between acetic acid (CH3COOH) and phosphorus pentachloride (PCl5). 

Option D is incorrect because it proposes the formation of H2, which is not a product of the reaction between CH3COOH and PCl5. The reaction primarily involves the substitution of hydroxyl (-OH) groups in acetic acid with chlorine atoms from PCl5. 

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Tagged under Chemistry · Carboxylic Acids and its Derivatives · 2011