Chemistry · Alcohols, Phenols and Ether
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When ethanol is warmed with ethanoic acid in the presence of a strong acid catalyst, an ester ethyl ethanoate is formed.
CH3CH2OH + CH3CO2H → CH3CO2CH2CH3
During this reaction:
- A
Alcohol is reduced
- B
O-H bond in ethanoic acid is broken
- C
O-H bond in ethanol is broken
- D
Acid is oxidised
In the given reaction, ethanol and ethanoic acid react in the presence of a strong acid catalyst (usually concentrated sulphuric acid) to form an ester, ethyl ethanoate. This reaction is an example of an esterification reaction.
The reaction involves the breaking of the O-H bond in the ethanol molecule and the O-H bond in the carboxylic acid molecule. The hydrogen from the -OH group of the ethanol combines with the hydroxyl group (-OH) of the carboxylic acid, leading to the formation of a water molecule. The remaining carbon-oxygen bond in both the ethanol and the carboxylic acid forms the ester linkage (-COO-) of the ester product.
Therefore, option (C) is the correct answer.
Option A is incorrect because reduction involves gaining electrons, which is not happening to the alcohol (ethanol) during the formation of ethyl ethanoate.
Option B is incorrect because the reaction does not involve breaking the O-H bond in ethanoic acid. Instead, the carbonyl group (C=O) in ethanoic acid reacts with ethanol.
In the given reaction, ethanol and ethanoic acid react in the presence of a strong acid catalyst (usually concentrated sulphuric acid) to form an ester, ethyl ethanoate. This reaction is an example of an esterification reaction.
The reaction involves the breaking of the O-H bond in the ethanol molecule and the O-H bond in the carboxylic acid molecule. The hydrogen from the -OH group of the ethanol combines with the hydroxyl group (-OH) of the carboxylic acid, leading to the formation of a water molecule. The remaining carbon-oxygen bond in both the ethanol and the carboxylic acid forms the ester linkage (-COO-) of the ester product.
Therefore, option (C) is the correct answer.
Option D is incorrect because the acid (ethanoic acid) is not being oxidized; it is participating in the reaction as a reactant and not undergoing any change in oxidation state.
Tagged under Chemistry · Alcohols, Phenols and Ether · 2012