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MDCAT
Chemistry
2023

Chemistry · Reaction Kinetics

Work through this past-paper style MCQ, then read the full explanation. Practice more chemistry questions on mMCQ with adaptive practice and topic analytics.

Question

Reaction that follows third order kinetics is:

Options
  • A

    Decomposition of nitrogen dioxide

  • B

    Decomposition of hydrogen iodide

  • C

    Gas phase oxidation of nitric oxide

  • D

    Formation of hydrogen iodide

Explanation

Option C is correct as gas phase oxidation of nitric oxide is a third order reaction. The reaction is as follows:

2NO(g) + O2(g) --> 2NO2(g)

This reaction is second order with respect to NO and first order with respect to O2, making the overall order to be 3. 

Option A and D are second order reaction and option B is a zero order reeaction.

Decomposition of NO2 is a second order reaction.

2NO2(g) --> 2NO(g) + O2(g)

Decomposition of Hydrogen iodide is a zero order reaction.

2HI(g) --> H2(g) + I2(g) 

Gas phase oxidation of nitric oxide is a third order reaction. The reaction is as follows:

2NO(g) + O2(g) --> 2NO2(g)

This reaction is second order with respect to NO and first order with respect to O2, making the overall order to be 3.

Formation of hydrogen iodide is a second order reaction.

H2(g) + I2(g) --> 2HI(g)

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Tagged under Chemistry · Reaction Kinetics · 2023