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MDCAT
Chemistry
2016

Chemistry · Analytical Chemistry

Work through this past-paper style MCQ, then read the full explanation. Practice more chemistry questions on mMCQ with adaptive practice and topic analytics.

Question

Chemical shift in NMR spectroscopy is expressed as delta (δ) or tan (t) scale. Choose the correct relationship between δ and t:

Options
  • A

    δ = 10 – t

  • B

    δ = 10 + t

  • C

    t = δ – 10

  • D

    t = 10 – δ

Explanation

In NMR spectroscopy, δ (delta) represents the chemical shift, while t is another scale used to express the same concept. The correct relationship between these two scales is δ = 10 – t. This means that to convert from the t scale to the δ scale, you subtract the tan value from 10. The other options are incorrect because they either add instead of subtract, reverse the roles of δ and t, or suggest a subtraction that doesn't reflect the true relationship.

This is the correct relationship between δ (delta) and tan (t) scales in NMR spectroscopy, where δ is calculated by subtracting t from 10.

This option is incorrect. Adding t to 10 does not correctly represent the conversion between the δ and t scales.

This option is incorrect. It wrongly suggests that t is calculated by subtracting 10 from δ, which is not the case.

This option is incorrect. Although it appears similar to the correct relationship, it reverses the roles of δ and t, leading to an incorrect expression.

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Tagged under Chemistry · Analytical Chemistry · 2016