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MDCAT
Chemistry
2021

Chemistry · Aldehydes and Ketones

Work through this past-paper style MCQ, then read the full explanation. Practice more chemistry questions on mMCQ with adaptive practice and topic analytics.

Question

Aldehyde reacts with Ammonia to form all of the following except:

Options
  • A

    Amine

  • B

    Imine

  • C

    Nitrile

  • D

    Hydrazones 

Explanation

OPTION A: Aldehydes react with ammonia to form a primary amine through Hartmann's nitration or Hofmann rearrangement.

OPTION B: The reaction of aldehydes and ketones with ammonia or 1°-amines forms imine derivatives, also known as Schiff bases (compounds having a C=N function). Water is eliminated in the reaction, which is acid-catalyzed and reversible in the same sense as acetal formation.

OPTION C: Aldehydes react with ammonia to form nitriles. Nitriles are a functional group in organic chemistry that contains a carbon atom triple-bonded to a nitrogen atom.

OPTION D: Aldehydes can react with hydrazine (NH2-NH2) to form Hydrazones, which are compounds containing a hydrazone group (-C=N-NH-).

Aldehydes react with ammonia to form a primary amine through Hartmann's nitration or Hofmann rearrangement.

The reaction of aldehydes and ketones with ammonia or 1°-amines forms imine derivatives, also known as Schiff bases (compounds having a C=N function). Water is eliminated in the reaction, which is acid-catalyzed and reversible in the same sense as acetal formation.

Aldehydes react with ammonia to form nitriles. Nitriles are a functional group in organic chemistry that contains a carbon atom triple-bonded to a nitrogen atom. 

Aldehydes can react with hydrazine (NH2-NH2) to form Hydrazones, which are compounds containing a hydrazone group (-C=N-NH-).

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Tagged under Chemistry · Aldehydes and Ketones · 2021