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A Levels Chemistry (9701)•9701/13/O/N/24
Question 39 from 9701/13/O/N/24

Explanation

Monomers identified from copolymer repeating units

Steps:

  • Analyze the polymer chain for two distinct repeating segments derived from alkene monomers.
  • Match the first segment: a three-carbon unit with chlorines on adjacent carbons, indicating 1,2-dichloropropene as the source.
  • Match the second segment: a four-carbon unit with a chlorine on the central carbon and a double bond position, indicating 2-chlorobut-2-ene.
  • Verify copolymer formation via addition polymerization linking these monomers alternately.

Why A is correct:

  • 1,2-Dichloropropene provides the -CHCl-CHCl-CH2- unit, and 2-chlorobut-2-ene provides the -C(CH3)Cl-CH=CH- unit, matching the polymer's structure per addition copolymerization rules.

Why the others are wrong:

  • B: 2,3-Dichlorobutene has chlorines on carbons 2 and 3, not matching the three-carbon segment.
  • C: Chlorobutene is too vague and lacks the specific double bond position for the four-carbon unit.
  • D: Chloropropene lacks the vicinal dichlorides needed for the first segment.

Final answer: A

Topic: Polymerisation

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