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A Levels Chemistry (9701)•9701/12/O/N/24
Question 39 from 9701/12/O/N/24

Explanation

Addition Polymerization of Alkenes

Steps:

  • Monomer is prop-2-en-1-ol (CH₂=CHCH₂OH), with double bond between C2-C3.
  • Addition polymerization opens the C=C double bond, forming single bonds between monomers.
  • Carbon 1 (CH₂OH) becomes a side chain on C2.
  • Repeat unit is -[CH₂-CH(CH₂OH)]-.

Why B is correct:

  • B depicts -[CH₂-CH(CH₂OH)]-, matching the standard addition polymer structure where the double bond adds across C2-C3, per Markovnikov-free vinyl polymerization rules.

Why the others are wrong:

  • A: Shows linear -[CH₂CH₂CH₂OH]-, ignoring the branched alkene structure.
  • C: Includes ester linkage, assuming condensation instead of addition.
  • D: Places OH on the chain backbone, altering the monomer's connectivity.

Final answer: B

Topic: Polymerisation

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