A Levels Chemistry (9701)•9701/11/O/N/24

Explanation
Nitrile hydrolysis to acid, then reduction to primary alcohol Steps:
- Identify the starting nitrile as 2-methylpropanenitrile, (CH3)2CHCN.
- Acid hydrolysis with H+(aq) converts the nitrile to carboxylic acid X by adding H2O across the CN triple bond, yielding (CH3)2CHCOOH.
- Name X as 2-methylpropanoic acid based on the three-carbon chain with a methyl branch at position 2.
- LiAlH4 reduces the carboxylic acid X to alcohol Y, (CH3)2CHCH2OH, where the COOH becomes CH2OH.
- Classify Y as primary alcohol since the carbon with OH attaches to one alkyl group.
Why A is correct:
- Matches the IUPAC name 2-methylpropanoic acid for X and primary classification for Y, per reduction rule RCOOH → RCH2OH.
Why the others are wrong:
- B: 3-methylbutanoic acid has four carbons in chain ((CH3)2CHCH2COOH); Y remains primary, not tertiary.
- C: 3-methylpropanoic acid invalid naming (chain reverts to 2-methylpropanoic); Y primary, not secondary.
- D: Correct name for X but misclassifies Y as tertiary (OH on terminal CH2, not branched carbon).
Final answer: A
Topic: Nitrogen compounds
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