A Levels Chemistry (9701)•9701/11/O/N/24

Explanation
Cyanohydrin formation requires a carbonyl and asymmetric addition for chirality
Steps:
- Hydrogen cyanide (HCN) adds to aldehydes/ketones, converting the planar carbonyl carbon to a tetrahedral carbon with OH and CN groups.
- The product is a cyanohydrin; chirality occurs if this carbon has four different substituents.
- Examine each compound: alcohols lack carbonyls and do not form cyanohydrins, while symmetric carbonyls yield achiral products.
- Identify the option where the carbonyl carbon gains four distinct groups post-reaction.
Why C is correct:
- CH3CHO (acetaldehyde) reacts to form CH3CH(OH)CN; the central carbon bonds to H, CH3, OH, and CN—all different, creating a chiral center per the definition of chirality (four unique substituents).
Why the others are wrong:
- A: CH3CHOHCH3 is an alcohol with no carbonyl, so no cyanohydrin forms.
- B: CH3COCH3 (acetone) forms (CH3)2C(OH)CN; central carbon has two identical CH3 groups, so achiral.
- D: HCHO (formaldehyde) forms CH2(OH)CN; central carbon has two H atoms, so achiral.
Final answer: C
Topic: Carbonyl compounds
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