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A Levels Chemistry (9701)•9701/11/O/N/24
Question 23 from 9701/11/O/N/24

Explanation

Limiting reactant in catalytic converter reaction

Steps:

  • Reaction: 2NO + 2CO → N₂ + 2CO₂; molar masses NO=30 g/mol, CO=28 g/mol.
  • Moles: NO = 23/30 ≈ 0.767 mol; CO = 7/28 = 0.25 mol.
  • Limiting reactant CO (0.25/2 = 0.125 reaction units); produces 0.125 mol N₂ + 0.25 mol CO₂ = 0.375 mol total gas.
  • At room conditions (RTP, 24 dm³/mol), volume = 0.375 × 24 = 9.0 dm³.

Why C is correct:

  • Matches total product moles (0.375) × molar volume (24 dm³/mol) from ideal gas law at RTP.

Why the others are wrong:

  • A: Assumes only N₂ volume, ignoring CO₂.
  • B: Uses CO moles directly without stoichiometry.
  • D: Assumes excess NO reacts fully, overestimating products.

Final answer: C

Topic: Atoms, molecules and stoichiometry

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