A Levels Chemistry (9701)•9701/11/O/N/24

Explanation
Limiting reactant in catalytic converter reaction
Steps:
- Reaction: 2NO + 2CO → N₂ + 2CO₂; molar masses NO=30 g/mol, CO=28 g/mol.
- Moles: NO = 23/30 ≈ 0.767 mol; CO = 7/28 = 0.25 mol.
- Limiting reactant CO (0.25/2 = 0.125 reaction units); produces 0.125 mol N₂ + 0.25 mol CO₂ = 0.375 mol total gas.
- At room conditions (RTP, 24 dm³/mol), volume = 0.375 × 24 = 9.0 dm³.
Why C is correct:
- Matches total product moles (0.375) × molar volume (24 dm³/mol) from ideal gas law at RTP.
Why the others are wrong:
- A: Assumes only N₂ volume, ignoring CO₂.
- B: Uses CO moles directly without stoichiometry.
- D: Assumes excess NO reacts fully, overestimating products.
Final answer: C
Topic: Atoms, molecules and stoichiometry
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