A Levels Chemistry (9701)•9701/13/O/N/23

Explanation
Redox and reactivity in group 2 metal-water reactions
Steps:
- Group 2 metals (Ca, Sr) react with water: 2M + 2H₂O → 2MOH + H₂, where M is oxidized (loses electrons to M²⁺) and water reduced (gains electrons to H₂ and OH⁻).
- Oxidation half: M → M²⁺ + 2e⁻; reduction half: 2H₂O + 2e⁻ → H₂ + 2OH⁻.
- Reactivity increases down group 2: Sr more reactive than Ca, so Sr + water more vigorous (faster H₂ evolution).
- Match to options: Substance reduced is water, oxidized is Ca or Sr; vigorous reaction is Sr + water.
Why D is correct:
- D accurately identifies water reduced (to H₂) and Sr oxidized (to Sr²⁺), with Sr's higher reactivity causing vigorous reaction per group 2 trend.
Why the others are wrong:
- A: Reverses redox (metals oxidized, not reduced) and picks less vigorous Ca.
- B: Reverses redox (water oxidized, not reduced) despite correct vigorous Sr.
- C: Correct redox but wrongly picks less vigorous Ca over Sr.
Final answer: D
Topic: Group 2
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