A Levels Chemistry (9701)•9701/12/O/N/23

Explanation
Nucleophilic addition involves a nucleophile attacking an electron-deficient center like a carbonyl carbon.
Steps:
- Recall that nucleophilic addition features a nucleophile adding to a π-bond or electrophilic center without substitution.
- Examine option A: alkene + HBr is electrophilic addition via carbocation intermediate.
- Examine option B: alkyl halide + NaOH in ethanol favors elimination (E2) over substitution.
- Examine option C: ketone + HCN involves CN⁻ nucleophile adding to C=O carbonyl.
- Examine option D: alkane + Cl₂ is free radical substitution.
Why C is correct:
- Propanone (CH₃COCH₃) reacts with HCN via nucleophilic addition, where CN⁻ attacks the electrophilic carbonyl carbon, forming a cyanohydrin (R₂C(OH)CN).
Why the others are wrong:
- A: Electrophilic addition, with H⁺ adding first to the alkene π-bond.
- B: Primarily E2 elimination in ethanolic NaOH, removing HBr to form alkene.
- D: Free radical chain reaction, with Cl• abstracting H from methane.
Final answer: C
Topic: Carbonyl compounds
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