A Levels Chemistry (9701)•9701/13/O/N/22

Explanation
Cis configuration in 1,4-addition polymerization
Steps:
- Buta-1,3-diene (CH2=CH-CH=CH2) undergoes 1,4-addition in polymerization.
- In cis-polybutadiene, the polymer chain forms with a double bond between carbons 2 and 3.
- The cis isomer has the chain substituents on the same side of the double bond.
- Repeat unit is -CH2-CH=CH-CH2- with cis geometry.
Why C is correct:
- C depicts the 1,4-repeat unit with cis double bond, as defined for cis-polybuta-1,3-diene.
Why the others are wrong:
- A: Shows 1,2-addition (pendant vinyl group), not 1,4-cis.
- B: Displays trans double bond configuration.
- D: Indicates saturated chain, lacking the required double bond.
Final answer: C
Topic: Polymerisation
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