A Levels Chemistry (9701)•9701/13/O/N/22

Explanation
Acid-catalyzed formation of mixed carboxylic anhydride
Steps:
- Identify the reaction as dehydration between two carboxylic acids under acidic conditions to form a mixed anhydride.
- Ethanoic acid is CH₃COOH (C₂H₄O₂); the product structure implies involvement of formic acid (HCOOH).
- Formic acid (CH₂O₂) + ethanoic acid → mixed anhydride CH₃C(O)OCHO + H₂O.
- Confirm molecular formula of X matches formic acid, CH₂O₂, based on product's carbon-oxygen framework.
Why D is correct:
- CH₂O₂ is the formula for formic acid (HCOOH), which forms the mixed anhydride with ethanoic acid, matching the product's structure and reaction type.
Why the others are wrong:
- A: C₂H₄O (e.g., acetaldehyde) forms acetals or other products, not the shown anhydride.
- B: C₂H₄O₂ is ethanoic acid itself; self-reaction yields symmetric anhydride, not the mixed product shown.
- C: C₂H₆O (ethanol) undergoes esterification to ethyl ethanoate, not the anhydride structure.
Final answer: D
Topic: Carboxylic acids and derivatives
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