A Levels Chemistry (9701)•9701/13/O/N/22

Explanation
Cyanohydrin Formation via Nucleophilic Addition
Steps:
- KCN dissociates to provide CN⁻ nucleophile, while HCN maintains equilibrium.
- CN⁻ attacks the electrophilic carbonyl carbon of the aldehyde (ethanal, likely intended over ethanol).
- This forms a tetrahedral alkoxide intermediate.
- Protonation of the alkoxide yields the hydroxynitrile product.
Why B is correct:
- B depicts CN⁻ addition to the carbonyl, the defining first step in base-catalyzed nucleophilic addition per organic mechanism principles.
Why the others are wrong:
- A: Involves H⁺ addition, which is acid-catalyzed path, not initial with KCN base.
- C: Shows deprotonation of HCN last, ignoring prior CN⁻ generation.
- D: Describes product formation directly, skipping nucleophilic attack.
Final answer: B
Topic: Carbonyl compounds
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