A Levels Chemistry (9701)•9701/12/O/N/22

Explanation
Electrophilic addition to alkynes with HBr
Steps:
- Compound R is an alkyne, undergoing electrophilic addition with HBr.
- First HBr adds following Markovnikov's rule, forming a vinyl halide intermediate.
- Excess HBr leads to a second addition, yielding a geminal dibromide.
- The major product is the 1,1-dibromoalkane from double Markovnikov addition.
Why A is correct:
- A shows the geminal dibromide, consistent with Markovnikov addition to terminal alkynes per HBr's mechanism.
Why the others are wrong:
- B is the monobromoalkene, incorrect as excess HBr drives to dibromide.
- C is the anti-Markovnikov monobromoalkene, wrong without peroxides.
- D is the vicinal dibromide, incorrect as additions to alkynes yield geminal products.
Not enough information on compound R structure.
Final answer: A
Topic: Hydroxy compounds
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