A Levels Chemistry (9701)•9701/11/O/N/22

Explanation
Cyanohydrin formation mechanism Steps:
- KCN dissociates to provide CN⁻ nucleophile in the HCN buffer system.
- CN⁻ attacks the electrophilic carbonyl carbon of the aldehyde (ethanal, likely intended over ethanol).
- This forms a tetrahedral alkoxide intermediate, R-CH(O⁻)CN.
- Protonation of the alkoxide by HCN yields the hydroxynitrile product, regenerating CN⁻. Why B is correct:
- B describes nucleophilic addition of CN⁻ to the carbonyl, the rate-determining step per organic mechanism principles. Why the others are wrong:
- A: Protonation of carbonyl occurs in acid-catalyzed paths, not base-assisted here.
- C: Deprotonation of HCN is prior equilibrium, not the first mechanistic step.
- D: CN⁻ departure is irrelevant, as this is addition, not substitution.
Final answer: B
Topic: Carbonyl compounds
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