A Levels Chemistry (9701)•9701/11/O/N/22

Explanation
Iodoform reaction produces CHI₃ precipitate and specific carboxylate ions
Steps:
- Alkaline I₂(aq) performs iodoform test on methyl ketones (CH₃COR), forming yellow CHI₃ precipitate and RCO₂⁻ ions.
- Yellow precipitate identifies CHI₃; CH₃CO₂⁻ requires R = CH₃, so W = CH₃COCH₃ (propanone).
- Butanone (CH₃COCH₂CH₃) has R = CH₂CH₃, yielding CH₃CH₂CO₂⁻ instead.
- Options list CH₃I (not yellow precipitate) for all, mismatching CHI₃.
Why A is wrong:
- Butanone forms propanoate (CH₃CH₂CO₂⁻), not acetate; CH₃I is incorrect precipitate.
Why the others are wrong:
- B: No information provided.
- C: Propanone correct for CH₃CO₂⁻ but CH₃I wrong precipitate.
- D: Identical to C, incorrect precipitate.
Not enough information.
Final answer: Not enough information.
Topic: Carbonyl compounds
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