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A Levels Chemistry (9701)•9701/11/O/N/22
Question 26 from 9701/11/O/N/22

Explanation

Alcohols are isomers if they share the same molecular formula but differ in structure

Steps:

  • Determine molecular formulas for each alcohol: count carbons and hydrogens, adding OH.
  • Butan-1-ol: CH₃CH₂CH₂CH₂OH (C₄H₁₀O); 2-methylpropan-1-ol: (CH₃)₂CHCH₂OH (C₄H₁₀O).
  • Pentan-1-ol: CH₃(CH₂)₃CH₂OH (C₅H₁₂O); propan-1-ol: CH₃CH₂CH₂OH (C₃H₈O); propan-2-ol: CH₃CH(OH)CH₃ (C₃H₈O); 2-methylpropan-2-ol: (CH₃)₃COH (C₄H₁₀O).
  • Compare pairs: only option A matches formulas (both C₄H₁₀O).

Why A is correct:

  • Both have formula C₄H₁₀O but different carbon chains: straight vs. branched.

Why the others are wrong:

  • B: Pentan-1-ol (C₅H₁₂O) vs. 2-methylpropan-1-ol (C₄H₁₀O); different carbon count.
  • C: Propan-1-ol (C₃H₈O) vs. 2-methylpropan-1-ol (C₄H₁₀O); different carbon count.
  • D: Propan-2-ol (C₃H₈O) vs. 2-methylpropan-2-ol (C₄H₁₀O); different carbon count.

Final answer: A

Topic: Hydroxy compounds

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