A Levels Chemistry (9701)•9701/13/O/N/21

Explanation
Isoelectronic ions share the same electron configuration as noble gas atoms.
Steps:
- Kr has atomic number 36 and configuration [Ar]4s²3d¹⁰4p⁶, with 36 electrons.
- X⁻ has the same configuration, so X⁻ also has 36 electrons.
- Neutral atom X has one fewer electron than X⁻, totaling 35 electrons.
- Element with 35 electrons is Br, with configuration [Ar]4s²3d¹⁰4p⁵.
Why B is correct:
- B matches Br's configuration, where adding one electron forms Br⁻ isoelectronic with Kr (same 36 electrons, per Aufbau principle).
Why the others are wrong:
- A: Matches Kr itself, so X⁺ would be isoelectronic, not X⁻.
- C: Identical to A; incorrect for neutral X.
- D: Matches Se (34 electrons); Se²⁻ is isoelectronic with Kr, not Se⁻ or similar.
Final answer: B
Topic: Atomic structure
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