A Levels Chemistry (9701)•9701/13/O/N/21

Explanation
LiAlH4 reduces 1,2-diketones to vicinal diols Steps:
- The product, 4-methylpentane-2,3-diol, is a vicinal diol with OH groups on adjacent carbons 2 and 3.
- LiAlH4 selectively reduces ketones to secondary alcohols without affecting other functional groups.
- A vicinal diol forms from reduction of a 1,2-diketone, where both carbonyls become OH groups.
- Thus, compound R is 4-methylpentane-2,3-dione, matching the carbon skeleton and positions.
Why A is correct:
- Option A is 4-methylpentane-2,3-dione, the exact 1,2-diketone that reduces to the given diol via two ketone-to-alcohol conversions.
Why the others are wrong:
- B: A single ketone reduces to a monoalcohol, not a diol.
- C: Ester groups reduce to alcohols but yield different chain lengths or primary alcohols.
- D: Aldehyde-ketone mix produces a primary-secondary diol, mismatched to the product's secondary-secondary pattern.
Final answer: A
Topic: Carbonyl compounds
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