mMCQ.

Navigation Menu

Step into mMCQ.

Launch mMCQ. diagnostic

Explore mMCQ.

MDCAT prepFree DiagnosticPricing & SubscribeSign in

Resources

Terms & Conditions

mMCQ.

© 2021 - 2025 mMCQ.All rights reserved.

WhatsApp
A Levels Chemistry (9701)•9701/13/O/N/21
Question 27 from 9701/13/O/N/21

Explanation

LiAlH4 reduces 1,2-diketones to vicinal diols Steps:

  • The product, 4-methylpentane-2,3-diol, is a vicinal diol with OH groups on adjacent carbons 2 and 3.
  • LiAlH4 selectively reduces ketones to secondary alcohols without affecting other functional groups.
  • A vicinal diol forms from reduction of a 1,2-diketone, where both carbonyls become OH groups.
  • Thus, compound R is 4-methylpentane-2,3-dione, matching the carbon skeleton and positions.

Why A is correct:

  • Option A is 4-methylpentane-2,3-dione, the exact 1,2-diketone that reduces to the given diol via two ketone-to-alcohol conversions.

Why the others are wrong:

  • B: A single ketone reduces to a monoalcohol, not a diol.
  • C: Ester groups reduce to alcohols but yield different chain lengths or primary alcohols.
  • D: Aldehyde-ketone mix produces a primary-secondary diol, mismatched to the product's secondary-secondary pattern.

Final answer: A

Topic: Carbonyl compounds

Practice more A Levels Chemistry (9701) questions on mMCQ.me