A Levels Chemistry (9701)•9701/13/O/N/21

Explanation
Role of CH3CO2H in alkene formation via elimination
Steps:
- Identify the reaction as E2 elimination from a vicinal dihalide or alkyl halide to form hex-2-ene.
- Note CH3CO2H provides CH3CO2⁻ ions, which abstract a proton from the β-carbon.
- Confirm bond breaking: C-H heterolytic, C-I heterolytic, forming C=C double bond.
- Classify CH3CO2⁻ as proton acceptor, making it a Brønsted-Lowry base.
Why A is correct:
- CH3CO2H dissociates to CH3CO2⁻ + H⁺; CH3CO2⁻ accepts H⁺ from substrate, fitting Brønsted-Lowry base definition (proton acceptor).
Why the others are wrong:
- B: No change in oxidation state of carbon; it's elimination, not oxidation.
- C: E2 involves heterolytic fission of C-I bond, not homolytic (which forms radicals).
- D: Hydrolysis adds water across a bond; this is dehydration-like elimination without net water addition.
Final answer: A
Topic: Halogen compounds
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