A Levels Chemistry (9701)•9701/13/O/N/21

Explanation
Group 2 sulfates exhibit solubility in water Steps:
- Apply standard solubility rules: group 2 chlorides and hydroxides are generally soluble, but carbonates and some hydroxides are not; sulfates are mostly soluble.
- Check option A: BaCl₂ soluble, but CaCO₃ (carbonate) and Mg(OH)₂ (hydroxide) insoluble.
- Check option B: Ba(OH)₂ and Ca(OH)₂ soluble, but SrCO₃ (carbonate) insoluble.
- Check option C: BaSO₄, CaSO₄, MgSO₄ all group 2 sulfates, soluble per rules.
- Check option D: BaSO₄ and CaSO₄ soluble, but Mg(OH)₂ insoluble.
Why C is correct:
- Solubility rules state sulfates of group 2 metals (Mg²⁺, Ca²⁺, Ba²⁺) dissolve in water, forming aqueous solutions.
Why the others are wrong:
- A: Contains insoluble CaCO₃ (carbonates of group 2 insoluble) and Mg(OH)₂ (sparingly soluble hydroxide).
- B: Contains insoluble SrCO₃ (group 2 carbonates insoluble).
- D: Contains insoluble Mg(OH)₂ (group 2 hydroxide with low solubility).
Final answer: C
Topic: Group 2
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