A Levels Chemistry (9701)•9701/12/O/N/21

Explanation
Optical isomers share identical atomic composition
Steps:
- Identify optical isomers as enantiomers: non-superimposable mirror images of each other.
- Recognize they have the same atoms bonded in the same order, differing only in 3D arrangement.
- Recall empirical formula as the simplest whole-number ratio of elements present.
- Conclude this ratio is unchanged by spatial configuration, making it identical for the pair.
Why A is correct:
- Optical isomers are stereoisomers with the same molecular formula by definition, so their empirical formula—the reduced ratio of atoms—is exactly the same.
Why the others are wrong:
- B: Functional groups depend on connectivity, which is identical, but empirical formula specifically addresses composition, not group types.
- C: Structural formula shows atom connections, which match, but it excludes the spatial difference defining optical isomerism.
- D: Not enough information.
Final answer: A
Topic: An introduction to organic chemistry
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