A Levels Chemistry (9701)•9701/12/O/N/21

Explanation
Carbonyl compound positive for both DNP and iodoform tests
Steps:
- 2,4-DNP reagent forms a yellow precipitate with aldehydes and ketones, confirming carbonyl presence.
- Alkaline aqueous iodine (iodoform test) gives a yellow precipitate with methyl ketones (CH3COR) or acetaldehyde.
- Eliminate A (butan-2-ol), an alcohol without a carbonyl group, so no DNP reaction.
- Among carbonyls (B, C, D), identify methyl ketone structure for iodoform: butanone (CH3COCH2CH3) qualifies, while butanal (CH3CH2CH2CHO) and pentan-3-one (CH3CH2COCH2CH3) do not.
Why C is correct:
- Butanone is a methyl ketone (CH3CO- group), forming hydrazone with DNP and iodoform with alkaline iodine per standard organic test definitions.
Why the others are wrong:
- A: Secondary alcohol lacks carbonyl, fails DNP test.
- B: Straight-chain aldehyde (not acetaldehyde) lacks CH3CO- for iodoform.
- D: Symmetrical ketone without CH3CO- group fails iodoform.
Final answer: C
Topic: Carbonyl compounds
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