A Levels Chemistry (9701)•9701/11/O/N/21

Explanation
Acetate ion acts as base in E2 elimination
Steps:
- Identify reaction: Hex-2-ene forms via elimination of HI from 2-iodohexane using CH3COO⁻.
- Determine mechanism: E2 involves base abstracting β-proton, leading to C-I heterolysis and alkene formation.
- Classify CH3COO⁻ role: It accepts H⁺ from β-carbon, fitting Bronsted-Lowry base definition.
- Evaluate options: Match roles to mechanism details.
Why A is correct:
- Bronsted-Lowry base accepts proton; CH3COO⁻ + H⁺ → CH3COOH in E2 step.
Why the others are wrong:
- B: No change in oxidation state; elimination preserves carbon skeleton without oxidation.
- C: E2 breaks C-I heterolytically (electrons to I⁻), not homolytically (radical).
- D: No water involvement; it's elimination with acetate, not hydrolysis.
Final answer: A
Topic: Halogen compounds
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