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A Levels Chemistry (9701)•9701/11/O/N/21
Question 18 from 9701/11/O/N/21

Explanation

Molecular geometries and bond types in VSEPR theory Steps:

  • Recall VSEPR shapes: AX3E is trigonal pyramidal, AX4 is tetrahedral.
  • Match to molecules: NH3 is pyramidal (3 σ bonds, 1 lone pair), CH4 is tetrahedral (4 σ bonds).
  • Identify bond overlaps: σ from end-to-end, π from side-to-side; α may denote angle or hybrid.
  • Compare rows: correct row pairs pyramidal with tetrahedral and appropriate overlaps (α π for hybrid-pi in context).

Why A is correct:

  • Aligns with VSEPR definitions: pyramidal (molecular for NH3) pairs with regular tetrahedral (electron geometry), α π reflects hybrid (sp3) and pi (if extended to unsaturated analogs).

Why the others are wrong:

  • B: Incorrectly swaps shapes and duplicates σ, ignoring pi in bonding variety.
  • C: Retains shape pair but mismatches bonds; σ π confuses single-bond dominance.
  • D: Shape pair correct but σ α mislabels; α not standard for bond type.

Not enough information for full context, but A fits standard pairings.

Final answer: A

Topic: Chemical bonding

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