A Levels Chemistry (9701)•9701/13/O/N/20

Explanation
Reduction in redox reactions involves gain of electrons
Steps:
- Identify oxidation states: In TiO2, Ti is +4 and O is -2; Cl2 is 0.
- In products, TiCl4 has Ti +4 and Cl -1; O2 has O 0.
- Compare changes: Cl decreases from 0 to -1 (gains electrons, reduced); O increases from -2 to 0 (oxidized); Ti unchanged.
- Confirm: Chlorine is reduced as it accepts electrons from oxygen.
Why B is correct:
- Chlorine is reduced because its oxidation state decreases from 0 in Cl2 to -1 in TiCl4, per the definition of reduction as electron gain.
Why the others are wrong:
- A: Carbon is not present in the reaction.
- C: Oxygen is oxidized, as its oxidation state increases from -2 to 0.
- D: Titanium's oxidation state remains +4 in both reactant and product.
Final answer: B
Topic: Chemistry of transition elements
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