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A Levels Chemistry (9701)•9701/13/O/N/20
Question 39 from 9701/13/O/N/20

Explanation

Esterification of primary alcohols produces water

Steps:

  • Identify the reaction type for each option involving primary alcohols.
  • Reaction 1: Acid-catalyzed esterification with ethanoic acid forms an ester.
  • Reaction 2: Nucleophilic substitution with concentrated HBr forms an alkyl bromide.
  • Reaction 3: Catalytic dehydration over heated Al2O3 forms an alkene.

Why A is correct:

  • Esterification follows the formula ROH + CH3COOH ⇌ CH3COOR + H2O, where water is eliminated as a by-product.

Why the others are wrong:

  • B: Substitution replaces -OH with -Br to give RBr directly; no water forms.
  • C: Dehydration removes H and OH to give an alkene; water is not a distinct product.

Final answer: A

Topic: Hydroxy compounds

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