A Levels Chemistry (9701)•9701/13/O/N/20

Explanation
Esterification of primary alcohols produces water
Steps:
- Identify the reaction type for each option involving primary alcohols.
- Reaction 1: Acid-catalyzed esterification with ethanoic acid forms an ester.
- Reaction 2: Nucleophilic substitution with concentrated HBr forms an alkyl bromide.
- Reaction 3: Catalytic dehydration over heated Al2O3 forms an alkene.
Why A is correct:
- Esterification follows the formula ROH + CH3COOH ⇌ CH3COOR + H2O, where water is eliminated as a by-product.
Why the others are wrong:
- B: Substitution replaces -OH with -Br to give RBr directly; no water forms.
- C: Dehydration removes H and OH to give an alkene; water is not a distinct product.
Final answer: A
Topic: Hydroxy compounds
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