A Levels Chemistry (9701)•9701/13/O/N/20

Explanation
Alkene structure, isomerism, and HBr addition rules
Steps:
- Draw 2-methylbut-1-ene: CH2=C(CH3)CH2CH3, with terminal double bond.
- Check geometrical isomers: C1 has two H atoms (identical substituents), so no cis-trans isomerism possible.
- Predict HBr addition: Markovnikov rule directs H to C1 (more hydrogens) and Br to C2, yielding CH3CBr(CH3)CH2CH3 (2-bromo-2-methylbutane).
- Compare to Student 2's product: 1-bromo-2-methylbutane is BrCH2CH(CH3)CH2CH3 (anti-Markovnikov, not major).
Why D is correct:
- Both statements fail: no geometrical isomers due to identical substituents on C1 (definition of cis-trans isomerism), and major HBr product is 2-bromo-2-methylbutane per Markovnikov's rule (H adds to carbon with more H's).
Why the others are wrong:
- A: Both students incorrect, as explained.
- B: Student 1 wrong; no geometrical isomers.
- C: Student 2 wrong; product is not 1-bromo-2-methylbutane.
Final answer: D
Topic: Hydrocarbons
Practice more A Levels Chemistry (9701) questions on mMCQ.me