A Levels Chemistry (9701)•9701/12/O/N/20

Explanation
Oxidation reagent for alcohol and aldehyde groups
Steps:
- Compound X has a primary alcohol and an aldehyde, both oxidizable.
- Acidified K2Cr2O7 oxidizes primary alcohols to carboxylic acids via aldehydes.
- It also oxidizes aldehydes directly to carboxylic acids.
- Other reagents target only one group, not both.
Why A is correct:
- Acidified potassium dichromate(VI), [O], oxidizes both -CH2OH to -COOH and -CHO to -COOH per standard organic oxidation rules.
Why the others are wrong:
- B. 2,4-DNP forms hydrazones only with carbonyls, ignoring alcohols.
- C. Hydrazine forms hydrazones with carbonyls but does not react with alcohols.
- D. NaBH4 reduces carbonyls to alcohols but leaves existing alcohols unchanged.
Final answer: A
Topic: Carbonyl compounds
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