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A Levels Chemistry (9701)•9701/12/O/N/20
Question 21 from 9701/12/O/N/20

Explanation

Naming the alcohol by identifying the longest chain and substituents

Steps:

  • Identify the longest carbon chain containing the OH group: pentane (5 carbons).
  • Number the chain to give the OH the lowest number: OH on carbon 2.
  • Identify substituents: two methyl groups on carbon 3.
  • Combine: 3,3-dimethylpentan-2-ol.

Why C is correct:

  • Follows IUPAC rules for alcohols: longest chain includes OH at lowest position, with geminal dimethyl at C3.

Why the others are wrong:

  • A: Wrong chain length and OH position; butane implies 4 carbons, not matching the structure.
  • B: Incorrect numbering and chain; ethyl substituent misidentifies branches.
  • D: Uses functional class name instead of substitutive (IUPAC prefers -ol suffix).

Final answer: C

Topic: Hydroxy compounds

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