A Levels Chemistry (9701)•9701/12/O/N/20

Explanation
Aluminum matches all oxide and bonding properties in Period 3
Steps:
- Period 3 candidates: Mg (group 2), Al (group 13), Si (group 14), P (group 15).
- Giant oxide structure: MgO and Al2O3 (ionic lattices); SiO2 (covalent lattice); excludes P (P4O10 molecular).
- Covalent Cl bonds: AlCl3, SiCl4, PCl5 covalent; excludes Mg (MgCl2 ionic).
- Oxide neutralizes HCl: MgO and Al2O3 react (basic/amphoteric); excludes Si (SiO2 acidic, inert to HCl) and P (P4O10 forms acid).
Why B is correct:
- Al2O3 giant ionic structure, AlCl3 covalent (dimer), Al2O3 + 6HCl → 2AlCl3 + 3H2O (acid-base reaction).
Why the others are wrong:
- A. Mg: MgCl2 ionic, not covalent.
- C. Si: SiO2 does not react with HCl(aq).
- D. P: P4O10 molecular structure, not giant.
Final answer: B
Topic: The Periodic Table: chemical periodicity
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