A Levels Chemistry (9701)•9701/11/O/N/20

Explanation
Reduction is gain of electrons or decrease in oxidation state
Steps:
- Assign oxidation states: Ti in TiO₂ is +4, O is -2; Cl in Cl₂ is 0.
- In products: Ti in TiCl₄ is +4, Cl is -1, O in O₂ is 0.
- Chlorine changes from 0 to -1, a decrease indicating reduction.
- Oxygen changes from -2 to 0, an increase indicating oxidation; Ti unchanged.
Why B is correct:
- Chlorine gains electrons as its oxidation state decreases from 0 in Cl₂ to -1 in TiCl₄, per the definition of reduction.
Why the others are wrong:
- A. Carbon does not appear in the reaction.
- C. Oxygen is oxidized, with oxidation state increasing from -2 to 0.
- D. Titanium's oxidation state remains +4 in both reactant and product.
Final answer: B
Topic: Chemistry of transition elements
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