A Levels Chemistry (9701)•9701/11/O/N/20

Explanation
Standard enthalpy of combustion of graphite equals formation of CO2(g) Steps:
- Define standard enthalpy of combustion for graphite: C(graphite) + O₂(g) → CO₂(g).
- Define standard enthalpy of formation for CO₂(g): same reaction, C(graphite) + O₂(g) → CO₂(g).
- Compare values: both are -393.5 kJ/mol by definition.
- Check other options using known values to confirm only C matches numerically. Why C is correct:
- By definition, ΔH°_comb(C, graphite) is identical to ΔH°_f(CO₂, g) as both describe the same reaction. Why the others are wrong:
- A: Atomisation of CH₄ requires ~1660 kJ/mol (endothermic); formation is -74.8 kJ/mol.
- B: Combustion of CH₄ is -890 kJ/mol; graphite + H₂ combustion sums to -680 kJ/mol.
- D: Neutralisation of HCl + NaOH is -57.1 kJ/mol; formation of H₂O(l) is -285.8 kJ/mol.
Final answer: C
Topic: Chemical energetics
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