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A Levels Chemistry (9701)•9701/11/O/N/20
Question 6 from 9701/11/O/N/20

Explanation

Standard enthalpy of combustion of graphite equals formation of CO2(g) Steps:

  • Define standard enthalpy of combustion for graphite: C(graphite) + O₂(g) → CO₂(g).
  • Define standard enthalpy of formation for CO₂(g): same reaction, C(graphite) + O₂(g) → CO₂(g).
  • Compare values: both are -393.5 kJ/mol by definition.
  • Check other options using known values to confirm only C matches numerically. Why C is correct:
  • By definition, ΔH°_comb(C, graphite) is identical to ΔH°_f(CO₂, g) as both describe the same reaction. Why the others are wrong:
  • A: Atomisation of CH₄ requires ~1660 kJ/mol (endothermic); formation is -74.8 kJ/mol.
  • B: Combustion of CH₄ is -890 kJ/mol; graphite + H₂ combustion sums to -680 kJ/mol.
  • D: Neutralisation of HCl + NaOH is -57.1 kJ/mol; formation of H₂O(l) is -285.8 kJ/mol.

Final answer: C

Topic: Chemical energetics

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