A Levels Chemistry (9701)•9701/11/O/N/20

Explanation
Determining molecular formula from skeletal structure
Steps:
- Count carbon atoms: the ring structure has 6 vertices, indicating 6 carbons.
- Identify heteroatoms: one oxygen attached to the ring, forming a hydroxyl group.
- Calculate hydrogens: each ring carbon has 1 H (5 from ring + 1 from OH), totaling 6 H for C6H6O.
- Verify formula: matches standard for phenolic compounds with aromatic ring.
Why A is correct:
- C6H6O follows the general formula for benzene derivatives like phenol, where the ring contributes C6H5 and OH adds H and O.
Why the others are wrong:
- B: Extra carbon would require additional bonds or chain, not present in the 6-carbon ring.
- C: Adds 4 extra hydrogens, implying saturated structure, but ring shows unsaturation.
- D: Extra carbon and 2 fewer hydrogens suggest triple bond or different unsaturation, inconsistent with the diagram.
Final answer: A
Topic: An introduction to organic chemistry
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