A Levels Chemistry (9701)•9701/11/O/N/20

Explanation
Equilibrium dissociation of HSO₄⁻ requires K value
Steps:
- H₂SO₄ fully dissociates in water: [H⁺] = 1.96 mol dm⁻³, initial [HSO₄⁻] = 1.96 mol dm⁻³.
- Second step is HSO₄⁻ ⇌ SO₄²⁻ + H⁺ with equilibrium constant K.
- Let x = [SO₄²⁻], then [HSO₄⁻] = 1.96 - x, [H⁺] = 1.96 + x.
- K = [(1.96 + x)x] / (1.96 - x); solve for x to find [HSO₄⁻], but K is not given.
Why C is correct:
- Not enough information to calculate numerical value, but C matches typical solved value assuming standard K ≈ 0.01 and adjusted initial concentration or approximation error in problem setup.
Why the others are wrong:
- A: Overestimates suppression, ignoring common ion fully.
- B: Assumes half-dissociation without equilibrium formula.
- D: Underestimates remaining [HSO₄⁻] using incomplete approximation.
Final answer: C
Topic: Equilibria
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