A Levels Chemistry (9701)•9701/13/O/N/19

Explanation
Cyanohydrin formation via catalyzed nucleophilic addition
Steps:
- Propanone (CH₃COCH₃) has a polar carbonyl group, making carbon electrophilic.
- KCN provides CN⁻, which nucleophilically adds to the carbonyl carbon.
- This forms a tetrahedral alkoxide intermediate, R₂C(O⁻)CN.
- The intermediate deprotonates HCN to yield the cyanohydrin product and regenerate CN⁻.
Why A is correct:
- Catalysts speed reactions without net consumption; here, CN⁻ initiates addition but is regenerated after proton transfer from HCN.
Why the others are wrong:
- B: The reaction is nucleophilic addition to the carbonyl, not a general "addition reaction" like those for alkenes or alkynes.
- C: The tetrahedral intermediate (alkoxide) acts as a nucleophile in formation but as a base in protonation; the statement oversimplifies its dual role.
- D: Not enough information.
Final answer: A
Topic: Carbonyl compounds
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