A Levels Chemistry (9701)•9701/13/O/N/19

Explanation
Thermal decomposition mass loss identifies the Group 2 metal nitrate Steps:
- Calculate mass loss fraction: 3.2 g / 5.00 g = 0.64
- Decomposition reaction: M(NO3)₂ → MO + 2NO₂ + ½O₂; mass lost per mole = 108 g
- Molar mass of M(NO3)₂ = 108 g / 0.64 ≈ 169 g/mol; M ≈ 169 - 124 = 45 g/mol
- This value approximates calcium's atomic mass of 40, with 3.2 g loss matching calculated 3.29 g for Ca(NO3)₂ Why B is correct:
- For calcium (M=40), molar mass 164 g/mol yields 108/164 ≈ 0.66 mass loss fraction, giving 3.29 g loss from 5 g—matches observed 3.2 g per decomposition formula Why the others are wrong:
- A. Magnesium (M=24): 108/148 ≈ 0.73 fraction, 3.65 g loss—exceeds 3.2 g
- C. Strontium (M=88): 108/212 ≈ 0.51 fraction, 2.55 g loss—below 3.2 g
- D. Barium (M=137): 108/261 ≈ 0.41 fraction, 2.07 g loss—below 3.2 g
Final answer: B
Topic: Group 2
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