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A Levels Chemistry (9701)•9701/13/O/N/19
Question 13 from 9701/13/O/N/19

Explanation

Period 3 trends in ionization energy and melting points identify Y as phosphorus

Steps:

  • Period 3 elements are Na to Ar; select consecutive trios from options.
  • First ionization energy (IE) rises across period with exceptions; melting point (MP) peaks for metals, drops for non-metals.
  • For Si-P-S, IE values: Si (786 kJ/mol), P (1012 kJ/mol), S (1000 kJ/mol); P has highest IE.
  • MP values: Si (1414°C), P (44°C), S (113°C); P has lowest MP, matching Y.

Why D is correct:

  • Phosphorus (Y) exhibits the highest first IE due to stable half-filled p subshell and lowest MP as molecular P4.

Why the others are wrong:

  • A: Mg has highest IE but MP (650°C) exceeds Na's (98°C).
  • B: Si has highest IE but highest MP (1414°C).
  • C: Identical to D, but assuming variant like P-S-Cl, S lacks highest IE (Cl=1251 kJ/mol).

Final answer: D

Topic: The Periodic Table: chemical periodicity

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