A Levels Chemistry (9701)•9701/13/O/N/19

Explanation
Period 3 trends in ionization energy and melting points identify Y as phosphorus
Steps:
- Period 3 elements are Na to Ar; select consecutive trios from options.
- First ionization energy (IE) rises across period with exceptions; melting point (MP) peaks for metals, drops for non-metals.
- For Si-P-S, IE values: Si (786 kJ/mol), P (1012 kJ/mol), S (1000 kJ/mol); P has highest IE.
- MP values: Si (1414°C), P (44°C), S (113°C); P has lowest MP, matching Y.
Why D is correct:
- Phosphorus (Y) exhibits the highest first IE due to stable half-filled p subshell and lowest MP as molecular P4.
Why the others are wrong:
- A: Mg has highest IE but MP (650°C) exceeds Na's (98°C).
- B: Si has highest IE but highest MP (1414°C).
- C: Identical to D, but assuming variant like P-S-Cl, S lacks highest IE (Cl=1251 kJ/mol).
Final answer: D
Topic: The Periodic Table: chemical periodicity
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