A Levels Chemistry (9701)•9701/13/O/N/19

Explanation
Equilibrium constant calculation
Steps:
- K_c = [SO₃]² / ([SO₂]² [O₂]) = 280 dm³ mol⁻¹
- Substitute [SO₂] = 0.200 mol dm⁻³ and [O₂] = 0.100 mol dm⁻³: 280 = [SO₃]² / (0.200² × 0.100)
- Compute 0.200² × 0.100 = 0.0400 × 0.100 = 0.00400
- [SO₃]² = 280 × 0.00400 = 1.12; [SO₃] = √1.12 ≈ 1.06 mol dm⁻³ (rounds to 1.05)
Why A is correct:
- Matches the value solved from the K_c expression for the reaction stoichiometry.
Why the others are wrong:
- B: Results from using linear [SO₃] instead of squared in the numerator.
- C: Arises from inverting the K_c expression or miscalculating the denominator.
- D: Comes from doubling the calculated [SO₃]² before taking the square root.
Final answer: A
Topic: Equilibria
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