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A Levels Chemistry (9701)•9701/13/O/N/19
Question 1 from 9701/13/O/N/19

Explanation

Catalysts lower activation energy without altering molecular energy distribution Steps:

  • Catalysts provide a pathway with reduced activation energy E_a, increasing reaction rate.
  • Maxwell-Boltzmann distribution shows energy distribution of molecules, fixed by temperature.
  • Peak of distribution (most probable energy) stays same height and position with catalyst.
  • E_a line shifts left to lower energy on x-axis (energy increasing rightward), increasing molecules above E_a.

Why B is correct:

  • Collision theory states catalysts decrease E_a (moving its position left), leaving distribution curve unchanged per Boltzmann distribution f(E) = (2/√π)(E^{1/2}/(kT)^{3/2}) exp(-E/kT).

Why the others are wrong:

  • A: Peak height unchanged; catalyst does not modify energy distribution.
  • C: E_a moves left (lower), not right (higher E_a would slow reaction).
  • D: Peak height and E_a position both unaffected or wrongly shifted.

Final answer: B

Topic: Reaction kinetics

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