A Levels Chemistry (9701)•9701/12/O/N/19

Explanation
Haloform reaction on secondary alcohol
Steps:
- Identify CH3CH(OH)CH3 as propan-2-ol (likely butan-2-ol intended for product match).
- Oxidize secondary alcohol to methyl ketone (e.g., CH3COCH2CH3).
- Apply haloform reaction: treat methyl ketone with excess halogen (I2/Br2) and NaOH.
- Cleave to haloform and carboxylic acid salt: RCOCH3 → RCOONa + CHI3.
Why C is correct:
- Excess NaOH with halogen (e.g., I2) enables haloform oxidation of methyl ketone to RCOONa, per the reaction CH3COR + 3X2 + 4NaOH → RCOONa + CHX3 + 3NaX + 3H2O.
Why the others are wrong:
- A: Na2CO3 is a weak base, insufficient for oxidation or haloform cleavage.
- B: NaOH alone deprotonates but does not oxidize alcohol to ketone or perform haloform.
- D: Not enough information (option incomplete).
Final answer: C
Topic: Hydroxy compounds
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