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A Levels Chemistry (9701)•9701/12/O/N/19
Question 34 from 9701/12/O/N/19

Explanation

Analyzing Reversible Reaction Energy Profiles

Steps:

  • Identify reactant and product energy levels: ΔH_forward = E_products - E_reactants.
  • Calculate backward enthalpy: ΔH_backward = -ΔH_forward.
  • Determine forward activation energy (E_a): energy from reactants to transition state peak.
  • Compare to diagram values for endothermic/exothermic nature.

Why A is correct:

  • By definition, ΔH_backward = -ΔH_forward; if forward ΔH = +20 kJ mol⁻¹ (products higher), backward is -20 kJ mol⁻¹.

Why the others are wrong:

  • B: Forward is exothermic (products lower than reactants), not endothermic.
  • C: Forward E_a is 30 kJ mol⁻¹ (peak 30 kJ above reactants), not 50 kJ mol⁻¹.
  • D: Not enough information (option incomplete).

Final answer: A

Topic: Reaction kinetics

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