A Levels Chemistry (9701)•9701/12/O/N/19

Explanation
Temperature Effect on Boltzmann Distribution Peak
Steps:
- Boltzmann distribution shows fraction of molecules with kinetic energies from 0 upward.
- Peak position is most probable energy, E_mp = (1/2) kT.
- Raising T raises kT term, shifting E_mp to higher value.
- On energy axis (increasing right), maximum moves right.
Why D is correct:
- Most probable energy formula E_mp = (1/2) kT directly ties peak position to T; higher T shifts it rightward.
Why the others are wrong:
- A: Peak moves right, not left, with higher T.
- B: Without diagram, [] representation ambiguous; not enough information.
- C: Without diagram, [] representation ambiguous; not enough information.
Final answer: D
Topic: Reaction kinetics
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