A Levels Chemistry (9701)•9701/11/O/N/19

Explanation
Intramolecular dehydration of a 1,2-diol to form an epoxide
Steps:
- Recognize CH3CH(OH)CH2OH as propane-1,2-diol, a vicinal diol.
- Conc. H2SO4 protonates one OH group, facilitating loss of water.
- The adjacent OH attacks the carbocation intramolecularly, forming a three-membered oxirane ring.
- Resulting structure is 2-methyloxirane with CH3 on the ring carbon.
Why C is correct:
- C shows the skeletal formula of 2-methyloxirane, the standard product from acid-catalyzed epoxide formation in 1,2-diols.
Why the others are wrong:
- A: Depicts a linear alkene, ignoring cyclization.
- B: Shows a four-membered ring, incorrect for 1,2-diol spacing.
- D: Illustrates a five-membered cyclic ether, requiring 1,4-diol geometry.
Final answer: C
Topic: Hydroxy compounds
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