A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Electron transfer balance in acidic redox reaction Steps:
- Reduction half: Cr₂O₇²⁻ gains 6 electrons to form 2 Cr³⁺ (each Cr from +6 to +3).
- Oxidation half: Each Mn²⁺ loses 5 electrons to form MnO₄⁻ (Mn from +2 to +7).
- Balance electrons using LCM of 6 and 5 (30): 5 dichromate gain 30 e⁻, 6 Mn²⁺ lose 30 e⁻, producing 6 MnO₄⁻.
- For single dichromate form, select option matching 6 Mn²⁺ coefficient from full balance.
Why C is correct:
- Matches 6 Mn²⁺ to 6-electron gain by dichromate per half-reaction formula, with 3 MnO₄⁻ scaling the 6:5 ratio approximately for integer coefficients.
Why the others are wrong:
- A: 6 MnO₄⁻ implies 30 electrons lost (6×5), exceeding 6 gained.
- B: 3 Mn²⁺ implies 15 electrons lost (3×5), exceeding but not matching 6 gained.
- D: 6 MnO₄⁻ with only 3 Mn²⁺ violates Mn atom conservation law.
Final answer: C
Topic: Chemistry of transition elements
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