A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Ideal gas law to find moles and mass of methane
Steps:
- Convert temperature to Kelvin: T = 60 + 273 = 333 K
- Calculate moles n = PV / RT with P = 103 kPa = 103000 Pa, V = 3.57 × 10^{-2} m³, R = 8.314 Pa m³/mol K
- Perform division: n = (103000 × 0.0357) / (8.314 × 333) ≈ 0.19 mol to two sig figs
- Compute mass = n × 16 g/mol = 3 g
Why C is correct:
- Ideal gas law PV = nRT gives n = PV / RT ≈ 0.19 mol; mass = n × molar mass (16 g/mol for CH₄) = 3 g to two sig figs
Why the others are wrong:
- A. Too small; assumes V in liters without unit conversion, yielding ~0.03 g
- B. Too small; assumes wrong R value or T in °C, yielding ~0.02 g
- D. Molar mass alone; assumes n = 1 mol, ignoring PV / RT calculation
Final answer: C
Topic: States of matter
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