A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Cyanohydrin formation via nucleophilic addition Steps:
- Recognize ethanol likely refers to ethanal (acetaldehyde, CH₃CHO) in this context, as alcohols do not form cyanohydrins.
- The reaction is CH₃CHO + HCN → CH₃CH(OH)CN, catalyzed by KCN (provides CN⁻).
- CN⁻ acts as nucleophile, attacking the electrophilic carbonyl carbon.
- This addition forms a new bond between the carbonyl carbon and the carbon of CN, with subsequent protonation of oxygen.
Why B is correct:
- Cyanohydrin formation follows nucleophilic addition mechanism where CN⁻ bonds to the carbonyl C, creating a C-C σ-bond (per organic reaction principles).
Why the others are wrong:
- A: No C-H bond breaks; the carbonyl C=O undergoes addition without H loss from carbon.
- C: No C-N bond exists or breaks; the CN group adds intact as a unit.
Final answer: B
Topic: Carbonyl compounds
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