A Levels Chemistry (9701)•9701/13/O/N/18

Explanation
Identifying the parent chain in IUPAC nomenclature
Steps:
- Examine the given name "3-2-bromo-methylbutane" for errors in structure and numbering.
- Identify the base hydrocarbon chain: "methylbutane" indicates a butane chain with a methyl substituent.
- Recognize that "3-2-bromo" is invalid numbering; the parent is the longest chain, which is butane with a methyl at position 2.
- Correct the name by removing the invalid bromo prefix, yielding 2-methylbutane as the base structure.
Why A is correct:
- In IUPAC rules, the parent chain is the longest continuous carbon chain; here, it's a 4-carbon butane with a methyl branch at carbon 2, forming 2-methylbutane.
Why the others are wrong:
- B: "2-bromo" is incomplete, lacking the full hydrocarbon name required for a compound.
- C: Repeats the original invalid name with improper hyphenation and numbering.
- D: "Bromo-methylbutane" omits locants, violating IUPAC specificity for substituent positions.
Final answer: A
Topic: Halogen compounds
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